SDS of cas: 123-11-5. Authors Yang, XJ; Gitter, SR; Roessler, AG; Zimmerman, PM; Boydston, AJ in WILEY-V C H VERLAG GMBH published article about in [Yang, Xuejin; Gitter, Sean R.; Boydston, Andrew J.] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA; [Roessler, Allison G.; Zimmerman, Paul M.] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA; [Roessler, Allison G.] Oglethorpe Univ, Dept Chem, Atlanta, GA 30319 USA; [Boydston, Andrew J.] Univ Wisconsin, Dept Mat Sci & Engn, Dept Chem & Biol Engn, Madison, WI 53706 USA in 2021.0, Cited 48.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
Stereochemistry can have a profound impact on polymer and materials properties. Unfortunately, straightforward methods for realizing high levels of stereocontrolled polymerizations are often challenging to achieve. In a departure from traditional metal-mediated ring-opening metathesis polymerization (ROMP), we discovered a remarkably simple method for controlling alkene stereochemistry in photoredox mediated metal-free ROMP. Ion-pairing, initiator sterics, and solvation effects each had profound impact on the stereochemistry of polynorbornene (PNB). Simple modifications to the reaction conditions produced PNB with trans alkene content of 25 to >98 %. High cis content was obtained from relatively larger counterions, toluene as solvent, low temperatures (-78 degrees C), and initiators with low Charton values. Conversely, smaller counterions, dichloromethane as solvent, and enol ethers with higher Charton values enabled production of PNB with high trans content. Data from a combined experimental and computational investigation are consistent with the stereocontrolling step of the radical cationic mechanism proceeding under thermodynamic control.
SDS of cas: 123-11-5. Welcome to talk about 123-11-5, If you have any questions, you can contact Yang, XJ; Gitter, SR; Roessler, AG; Zimmerman, PM; Boydston, AJ or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles